Chapter 5: Exploring Mixtures and Their Separation
Introduction:
Mixtures are combinations of two or more substances. Separation of mixtures is important in daily life, industries, and medical fields such as sugar production and blood testing.
Mixtures are combinations of two or more substances. Separation of mixtures is important in daily life, industries, and medical fields such as sugar production and blood testing.
5.1 Classification of Mixtures
Homogeneous Mixture: Uniform composition throughout.
Examples: Sugar solution, vinegar, soda.
Heterogeneous Mixture: Non-uniform composition.
Examples: Sand + water, oil + water.
Examples: Sugar solution, vinegar, soda.
Heterogeneous Mixture: Non-uniform composition.
Examples: Sand + water, oil + water.
Key Activity (Laser Test)
• Salt + water → No visible particles → Solution
• Chalk + water → Particles visible → Suspension
• Milk + water → Appears uniform but scatters light → Colloid
• Chalk + water → Particles visible → Suspension
• Milk + water → Appears uniform but scatters light → Colloid
5.2 Solutions
Solution: Homogeneous mixture of solute and solvent.
• Solute → Substance dissolved
• Solvent → Substance that dissolves solute
• Solute → Substance dissolved
• Solvent → Substance that dissolves solute
5.2.1 Concentration of Solution
Concentration = Amount of solute in a given amount of solvent/solution.
5.2.2 Methods to Express Concentration
1. Mass by Mass (% m/m)
Formula:
% m/m = (Mass of solute / Mass of solution) × 100
Example:
10g salt + 90g water = 100g solution
% m/m = (10/100) × 100 = 10%
% m/m = (Mass of solute / Mass of solution) × 100
Example:
10g salt + 90g water = 100g solution
% m/m = (10/100) × 100 = 10%
2. Mass by Volume (% m/v)
Formula:
% m/v = (Mass of solute / Volume of solution) × 100
Example:
5g glucose in 100 mL → 5%
% m/v = (Mass of solute / Volume of solution) × 100
Example:
5g glucose in 100 mL → 5%
3. Volume by Volume (% v/v)
Formula:
% v/v = (Volume of solute / Volume of solution) × 100
Example:
1 mL pesticide in 100 mL → 1%
% v/v = (Volume of solute / Volume of solution) × 100
Example:
1 mL pesticide in 100 mL → 1%
5.2.3 Solubility
Solubility = Maximum solute dissolved in 100g/100mL solvent at a given temperature.
• Increases with temperature (solids)
• Decreases with temperature (gases)
Saturated Solution: Cannot dissolve more solute.
• Increases with temperature (solids)
• Decreases with temperature (gases)
Saturated Solution: Cannot dissolve more solute.
5.3 Separation of Homogeneous Mixtures
1. Crystallization
Formation of pure crystals from saturated solution.
Principle: Solubility changes with temperature.
Steps:
• Prepare saturated solution
• Filter impurities
• Cool slowly → crystals form
Principle: Solubility changes with temperature.
Steps:
• Prepare saturated solution
• Filter impurities
• Cool slowly → crystals form
2. Distillation
Used to separate miscible liquids based on boiling points.
Principle:
Lower boiling liquid vaporises first → condenses → collected.
Example:
Acetone (56°C) + Water (100°C)
Principle:
Lower boiling liquid vaporises first → condenses → collected.
Example:
Acetone (56°C) + Water (100°C)
Fractional Distillation
Used when boiling point difference is small (<25°C).
Example: Petroleum refining
Example: Petroleum refining
3. Paper Chromatography
Separates substances based on movement rate on paper.
Principle:
Different substances move at different speeds.
Principle:
Different substances move at different speeds.
5.4 Separation of Heterogeneous Mixtures
1. Separating Funnel
Used for immiscible liquids (oil + water).
Based on density difference.
Based on density difference.
2. Sublimation
Solid → Vapour (without liquid stage)
Examples:
Camphor, naphthalene, dry ice
Examples:
Camphor, naphthalene, dry ice
3. Suspensions
• Heterogeneous
• Particles visible
• Settle on standing
Example: Muddy water
• Particles visible
• Settle on standing
Example: Muddy water
4. Centrifugation
Spinning separates heavier particles.
Example:
Blood separation
Example:
Blood separation
5. Coagulation
Small particles combine into larger ones.
Example:
Alum purifies water
Example:
Alum purifies water
5.4.4 Colloids
• Intermediate particle size (1–1000 nm)
• Do not settle
• Show Tyndall effect
Examples:
Milk, blood, ice cream
• Do not settle
• Show Tyndall effect
Examples:
Milk, blood, ice cream
5.5 Tyndall Effect
Scattering of light by particles.
Observed in:
• Fog
• Smoke
• Sunlight through trees
Observed in:
• Fog
• Smoke
• Sunlight through trees
Comparison Table
| Property | Solution | Suspension | Colloid |
|---|---|---|---|
| Nature | Homogeneous | Heterogeneous | Heterogeneous (appears uniform) |
| Particle Size | < 1 nm | > 1000 nm | 1–1000 nm |
| Visibility | Not visible | Visible | Not visible |
| Settling | No | Yes | No |
| Tyndall Effect | No | Yes | Yes |
Important Points
• Mixtures can be homogeneous or heterogeneous.
• Crystallization purifies solids.
• Distillation separates liquids.
• Chromatography separates colours.
• Sublimation separates special solids.
• Centrifugation separates heavy particles.
• Tyndall effect distinguishes colloids.
• Crystallization purifies solids.
• Distillation separates liquids.
• Chromatography separates colours.
• Sublimation separates special solids.
• Centrifugation separates heavy particles.
• Tyndall effect distinguishes colloids.
